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Bruker Corporation apex ii program suite
Apex Ii Program Suite, supplied by Bruker Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/apex+ii+program+suite/apex+ii+software/pm40180608-149-10-9
Average 90 stars, based on 1 article reviews
apex ii program suite - by Bioz Stars, 2026-10
90/100 stars

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Article Title: Tunable Emission and Structural Insights of 6-Arylvinyl-2,4-bis(2′-hydroxyphenyl)pyrimidines and Their O ∧ N ∧ O-Chelated Boron Complexes
Article Snippet: The raw data were integrated and corrected for Lorentz and polarization effects with the aid of the Bruker APEX II program suite.

Article Title: Mononuclear Cu-complex embedded ordered nano-porous silica based hybrid catalyst for oxidation of benzyl alcohol
Article Snippet: A novel mixed ligand copper ( ׀ ׀ ) complex having 2,9-dimethyl-1,10-phenanthroline and nitrate has been successfully synthesized and characterized by single crystal XRD.. Following synthesis, this complex was anchored on acid functionalized nano-porous materials such as MCM-41-SO3H and SBA-15-SO3H, and these hybrid materials were characterized using a variety of techniques such as FT-IR, PXRD, BET, SEM, TG, and so on.. These modified mesoporous materials (MCM-41-SO3H–Cu and SBA-15-SO3H–Cu) were subjected to solvent-free selective benzyl alcohol oxidation with TBHP (Tert-Butyl Hydroperoxide) as an oxidant.

Article Title: Reduction of nitrite to nitric oxide and generation of reactive chalcogen species by mononuclear Fe(II) and Zn(II) complexes of thiolate and selenolate.
Article Snippet: Comparative reactivity of a series of new Zn(II) and Fe(II) compounds, [(Py2ald)M(ER)] (E = S, R = Ph: M = Zn, 1a; M = Fe, 1a; E = S, R = 2,6-Me2-C6H3: M = Zn, 1b ; M = Fe, 1b; E = Se, R = Ph: M = Zn, 2; M = Fe, 2), and [(Py2ald)M]2 2+ (M = Zn, 5; M = Fe, 5) is presented.. Compound 1a could react with nitrite (NO2 ) to produce [(Py2ald)Zn(ONO)] (3), which, upon treatment with thiols and PhSeH (proton source), could regenerate either 1a/5 and 2 respectively, along with the production of nitric oxide (NO) where the yield of NO increases in the order BuSH ≪ PhCH2SH < PhSH < PhSeH.. In contrast to this, 1a, 2 and 5 could affect the direct reduction of NO2 − in the absence of protons to generate NO and [{(Py2ald)(ONO)Fe}2-μ2-O] (8 ).

Article Title: Functional Nonheme Diiron(II) Complexes Catalyze the Direct Reduction of Nitrite to Nitric Oxide in Relevance to the Diiron Protein YtfE.
Article Snippet: The present work reports the functional modeling chemistry of YtfE, which features a nonheme diiron active site and mediates the direct reduction of NO2 to NO.. The model complex, [Fe2(HPTP)Cl2] (1), reduces NO2 to NO in a 100% yield within 12 h and generates [Fe4(HPTP)2(μ-O)3(μ-OH)] (2).. Similar to YtfE, the reaction involves stepwise oxidation of two Fe(II) centers and product (NO) inhibition, of which the latter produces [Fe2(HPTP)(NO)2Cl2] (3).

Article Title: Synthesis and characterisation of divalent di(1,3‐bis(diphenylphosphano)cyclopentadienyl)lanthanoid and alkaline earth complexes as potential platforms for heterometallic complexes
Article Snippet: [30] Bruker AXS Ltd. Apex II Program Suite, 2005.

Article Title: Reduction of Nitrite in an Iron(II)-Nitrito Compound by Thiols and Selenol Produces Dinitrosyl Iron Complexes via an {FeNO} 7 Intermediate.
Article Snippet: Reaction of an Fe(II) complex, [Fe(6-COO−-tpa)]1+ (1), with PhE− and NO2 produced [Fe(6-COO−-tpa)(EPh)] (E = S, 2a; Se, 3) and [Fe(6-COO-tpa)(κ-O,O′-NO2)] (4), respectively (6-COOHtpa is bis(2-pyridylmethyl)(6-carboxyl-2-pyridylmethyl)amine).. Treatment of 4 with 2 equiv of PhEH (E = S, Se) produced NO in ∼40% yields, respectively, along with 1 and the DNICs, [Fe(EPh)2(NO)2] (E = S, Se).. Treatment of 4 with excess PhEH produced NO in similar yields, while 4 was converted to the same DNICs and 2a/3 (instead of 1).

Article Title: Carboxylate Bridged Binuclear Cobalt(II) Complexes Catalyze the Hydrolysis of Thiolates to Alcohols
Article Snippet: A binuclear Co(II) complex, [Co2(PhBIMP)(μ-O2CPh)(MeCN)] 2+ (1) (PhBIMP is the anion of 2,6-bis[(bis((N-1-methyl-4,5-diphenylimidazoylmethyl) amino)methyl]-4-methylphenol) catalyzes the hydrolysis of thiolates to the corresponding alcohols/phenols at room temperature.. Hydrolysis of 11 different thiolates has been investigated with a catalyst loading of 4–6.7 mol% and with the highest TON values reaching 22.. Furthermore, the effects of electron donating and electron withdrawing groups on the bridging benzoate of 1 have been investigated.

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Article Title: Generation and Reactivity of Polychalcogenide Chains in Binuclear Cobalt(II) Complexes
Article Snippet: .. Molecular structures of the 20 compounds, 1a(ClO4), 1b(BPh4), 2(ClO4), 3(ClO4), 4(ClO4), 4(BPh4), 5(ClO4), 6(BF4), 7(ClO4), 8(ClO4), 8(BPh4), 9a(ClO4)2, 9b(BPh4), 10(ClO4), 11(ClO4), 11(BPh4), 13a(BPh4), 13b(ClO4), 14 and 15 were determined by single crystal X-ray structure determination using a Bruker D8 VENTURE Microfocus diffractometer equipped with PHOTON II Detector, with Mo Kα radiation (λ = 0.71073 Å), controlled by the APEX3 (v2017.3−0) software package following a procedure similar to that reported previously by us.2 The Bruker APEX II program suite3 was used for integration of the raw data and correction for Lorentz and polarization effects, SADABS was used for absorption corrections, XPREP was used for assignment of space groups and PLATON4, 5 was used to check for additional symmetry. ..



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